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Flow of pH-responsive microcapsules in porous media


Type

Article

Change log

Authors

Gun, WJ 
Routh, AF 

Abstract

This article investigates the use micro-capsules, containing a gelling agent hydroxypropyl cellulose (HPC), to alter flow paths in porous media. The aim is to preferentially block-off high permeability regions, thereby diverting the flow into adjacent un-swept low permeability regions. Micro-capsules with 2 – 7 µm in diameter, were made by polymer precipitation through solvent evaporation usingpoly(4-vinyl pyridine) (PVP) as the shell material. A customized flow tank was constructed to facilitate porous media flow and both single and dual permeability experiments were conducted. Even without gelling agent, the micro-capsules gradually blocked the pore throats of the glass beads network. Following acidification a drop in permeability was observed. This was because swelling of the PVP shell constricted the pore throats. The permeability drop was observed to be more significant for low permeability regions. Flowing micro-capsules through the tank with two permeability regions in parallel, allowed the high permeability region to be selectively blocked.

Description

Keywords

Encapsulation, Enhanced oil recovery, Triggered release, Porous media

Journal Title

Chemical Engineering Science

Conference Name

Journal ISSN

0009-2509
1873-4405

Volume Title

123

Publisher

Elsevier BV
Sponsorship
Financial support from BP and Mr. Yousef Jameel is gratefully acknowledged.