A mechanochemical strategy for IRMOF assembly based on pre-designed oxo-zinc precursors.
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Abstract
We demonstrate a mechanochemical strategy that allowed the first successful mechanosynthesis of IRMOFs based on an oxo-centred secondary building unit (SBU). The presented study indicates that controlling the acid-base relationship between reagents is key to mechanochemical synthesis of IRMOFs, revealing a pre-assembled oxo-zinc amidate cluster as an efficient precursor for IRMOF mechanosynthesis.
Description
Journal Title
Chem Commun (Camb)
Conference Name
Journal ISSN
1359-7345
1364-548X
1364-548X
Volume Title
51
Publisher
Royal Society of Chemistry (RSC)
Publisher DOI
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Sponsorship
The authors would like to acknowledge the project operated within the Foundation for Polish Science Team Programme co-financed by the EU ‘‘European Regional Development Fund’’ TEAM/2011–7/8, and the European Union in the framework of Regional Development Fund through the Joint UW and WUT International PhD Program of Foundation for Polish Science – “Towards Advanced Functional Materials and Novel Devices” (MPD/2010/4) (D.P.) for financial support.