A mechanochemical strategy for IRMOFs assembly based on pre-designed oxo-zinc precursors
Royal Society of Chemistry
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Prochowicz, D., Sokołowski, K., Justyniak, I., Kornowicz, A., Fairen Jimenez, D., Friščić, T., & Lewiński, J. (2015). A mechanochemical strategy for IRMOFs assembly based on pre-designed oxo-zinc precursors. Chemical Communications, 51 4032-4035. https://doi.org/10.1039/C4CC09917F
We demonstrate a mechanochemical strategy that allowed the first successful mechanosynthesis of IRMOFs based on an oxo-centred SBU. The study indicates that controlling the acid-base relationships between reagents is key to mechanochemical synthesis of IRMOFs, and a pre-assembled oxo-zinc amidate cluster appeared as a very efficient precursor to IRMOFs.
The authors would like to acknowledge the project operated within the Foundation for Polish Science Team Programme co-financed by the EU ‘‘European Regional Development Fund’’ TEAM/2011–7/8, and the European Union in the framework of Regional Development Fund through the Joint UW and WUT International PhD Program of Foundation for Polish Science – “Towards Advanced Functional Materials and Novel Devices” (MPD/2010/4) (D.P.) for financial support.
External DOI: https://doi.org/10.1039/C4CC09917F
This record's URL: https://www.repository.cam.ac.uk/handle/1810/247457