Cobalt-catalysed C–H carbonylative cyclisation of aliphatic amides
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Peer-reviewed
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Abstract
A cobalt-catalysed C–H carbonylation of aliphatic carboxamide derivatives is described, employing commercially available Co(II)-salts in the presence of a silver oxidant. This operationally simple process utilises an atmospheric pressure of CO and generates a range of substituted succinimide products bearing diverse functional groups that can be successfully accessed via this methodology.
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Chemical Science
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2041-6520
2041-6539
2041-6539
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Royal Society of Chemistry
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Except where otherwised noted, this item's license is described as Attribution 4.0 International
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The Royal Society (wm140104)
European Research Council (259711)
Engineering and Physical Sciences Research Council (EP/I00548X/1)
European Research Council (259711)
Engineering and Physical Sciences Research Council (EP/I00548X/1)
We are grateful to the Herchel Smith Foundation for a scholarship (P. W.) and the Royal Society (Wolfson Merit Award, M. J. G) and the EPSRC (EP/100548X/1) and ERC (ERC-StG-259711) for Fellowships (M. J. G). Mass spectrometry data were acquired at the EPSRC UK National Mass Spectrometry Facility at Swansea University.