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Magnetic properties of monoclinic lanthanide orthoborates, LnBO3, Ln = Gd, Tb, Dy, Ho, Er, Yb

Accepted version
Peer-reviewed

Type

Article

Change log

Authors

Mukherjee, Paromita  ORCID logo  https://orcid.org/0000-0001-5121-6280
Lampronti, GI 
Dutton, SE 

Abstract

The lanthanide orthoborates, LnBO3, Ln = Gd, Tb, Dy, Ho, Er, Yb crystallise in a monoclinic structure with the magnetic Ln3+ forming an edge-sharing triangular lattice. The triangles are scalene, however all deviations from the ideal equilateral geometry are less than 1.5%. The bulk magnetic properties are studied using magnetic susceptibility, specific heat and isothermal magnetisation measurements. Heat capacity measurements show ordering features at T 2 K for Ln = Gd, Tb, Dy, Er. No ordering is observed for YbBO3 at T 0.4 K and HoBO3 is proposed to have a non-magnetic singlet state. Isothermal magnetisation measurements indicate isotropic Gd3+ spins and strong single-ion anisotropy for the other Ln3+. The change in magnetic entropy has been evaluated to determine the magnetocaloric effect in these materials. GdBO3 and DyBO3 are found to be competitive magnetocaloric materials in the liquid helium temperature regime.

Description

Keywords

Inorganic compounds, Magnetic properties, X-Ray diffraction, Crystal structure, Specific heat

Journal Title

Materials Research Bulletin

Conference Name

Journal ISSN

0025-5408
1873-4227

Volume Title

98

Publisher

Elsevier BV
Sponsorship
Engineering and Physical Sciences Research Council (EP/M000524/1)
Winton Programme for the Physics of Sustainability
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