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Dynamics of Ion Transport in Ionic Liquids.

Published version
Peer-reviewed

Type

Article

Change log

Authors

Lee, Alpha A 
Kondrat, Svyatoslav  ORCID logo  https://orcid.org/0000-0003-4448-0686
Goriely, Alain 

Abstract

A gap in understanding the link between continuum theories of ion transport in ionic liquids and the underlying microscopic dynamics has hindered the development of frameworks for transport phenomena in these concentrated electrolytes. Here, we construct a continuum theory for ion transport in ionic liquids by coarse graining a simple exclusion process of interacting particles on a lattice. The resulting dynamical equations can be written as a gradient flow with a mobility matrix that vanishes at high densities. This form of the mobility matrix gives rise to a charging behavior that is different to the one known for electrolytic solutions, but which agrees qualitatively with the phenomenology observed in experiments and simulations.

Description

Keywords

Anions, Cations, Ionic Liquids, Models, Chemical, Temperature

Journal Title

Phys Rev Lett

Conference Name

Journal ISSN

0031-9007
1079-7114

Volume Title

115

Publisher

American Physical Society (APS)

Rights

Publisher's own licence