The Hawaiian Island chain in the middle of the Pacific Ocean is a well-studied example of hotspot volcanism caused by an underlying upwelling mantle plume. The thermal and compositional nature of the plume alters the mantle phase transitions, which can be seen in the depth and amplitude of seismic discontinuities. This study utilises $>$ 5000 high quality receiver functions from Hawaiian island stations to detect P-to-s converted phases to image seismic discontinuities between 200 to 800 km depth. Common-conversion point stacks of the data are used to map out lateral variations in converted phase observations, while slowness stacks allow differentiation between true conversions from discontinuities and multiples. We find that the 410 discontinuity is depressed by 20 km throughout our study region, while the main 660 is around average depth throughout most of the area. To the southwest of the Big Island we observe splitting of the 660, with a major peak at 630 km, and a minor peak appearing at 675 km depth. This is inferred to represent the position of the hot plume at depth, with the upper discontinuity caused by an olivine phase transition and the lower by a garnet phase transition. In the upper mantle, a discontinuity is found across the region at depths varying between 290 to 350 km. Identifying multiples from this depth confirms the presence of a so-called X-discontinuity. To the east of the Big Island the X-discontinuity lies around 336 km and the associated multiple is particularly coherent and strong in amplitude. Strikingly, the discontinuity around 410 km disappears in this area. Synthetic modelling reveals that such observations can be explained by a silica phase transition from coesite to stishovite, consistent with widespread ponding of silica-saturated material at these depths around the plume. This material could represent eclogite enriched material, which is relatively silica-rich compared to pyrolite, spreading out from the plume to the east as a deep eclogite pool, a hypothesis which is consistent with dynamical models of thermochemical plumes. Therefore these results support the presence of a significant garnet and eclogite component within the Hawaiian mantle plume.