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Helium Diffraction as a Probe of Structure and Proton Order on Model Ice Surfaces.

Accepted version
Peer-reviewed

Type

Article

Change log

Authors

Allison, W 

Abstract

Helium diffraction has the potential to reveal the degree of proton order at an ice surface, and has been used in the past to benchmark theoretical work. We demonstrate that previous calculations do not represent the diffraction experiment to a sufficient degree of accuracy. By combining a realistic helium-water potential with quantum calculations using exact close-coupling methods we demonstrate that the scattering is strongly energy dependent. Proton order may be inferred best from selective adsorption resonances of the helium atom, which involve multiple scattering. We use the results to discuss the validity of the latest assumptions for the ice Ih surface with respect to proton ordering.

Description

Keywords

0202 Atomic, Molecular, Nuclear, Particle and Plasma Physics, 0306 Physical Chemistry (incl. Structural)

Journal Title

Journal of Physical Chemistry Letters

Conference Name

Journal ISSN

1948-7185
1948-7185

Volume Title

7

Publisher

American Chemical Society

Rights

All rights reserved
Sponsorship
For financial support, N.A. gratefully acknowledges the Blavatnik Foundation.