Quantitative Supramolecular Heterodimerization for Efficient Energy Transfer.
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Peer-reviewed
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Abstract
The challenge of quantitatively forming self-assembled heterodimers without other equilibrium by-products is overcome through self-sorting favored by the introduction of designed shape-complementary moieties. Such a supramolecular strategy based on cucurbit[8]uril-directed dimerization is further applied to generate hetero-chromophore dimers quantitatively, leading to efficient energy transfer (>85 %) upon photoexcitation.
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Angew Chem Int Ed Engl
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1433-7851
1521-3773
1521-3773
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59
Publisher
Wiley
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Except where otherwised noted, this item's license is described as All rights reserved
Sponsorship
European Research Council (726470)
Engineering and Physical Sciences Research Council (EP/L027151/1)
European Commission Horizon 2020 (H2020) Marie Sk?odowska-Curie actions (845640)
Engineering and Physical Sciences Research Council (EP/G060649/1)
Engineering and Physical Sciences Research Council (EP/L027151/1)
European Commission Horizon 2020 (H2020) Marie Sk?odowska-Curie actions (845640)
Engineering and Physical Sciences Research Council (EP/G060649/1)
This work was supported by Leverhulme Trust (“Natural material innovation for sustainable living”, G.W., O.A.S.), ERC-2016 Consolidator Grant (CAM-RIG, 726470, G.W., O.A.S.), EPSRC Programme Grant (NOtCH, EP/L027151/1, Z.H., O.A.S.), and Marie Skłodowska-Curie Fellowship (H2020-MSCA-IF-2018, 845640, Z.H.).