We present ALMA observations of a merging system at z ~ 4.57, observed as a part of the ALMA Large Program to INvestigate [CII] at Early times (ALPINE) survey. Combining ALMA [CII] 158 micron and far-infrared continuum data with multi-wavelength ancillary data we find that the system is composed of two massive (Mstar >~ 10^10 Msun) star-forming galaxies experiencing a major merger (stellar mass ratio r_mass ~ 0.9) at close spatial (~13 kpc; projected) and velocity (delta_v < 300 km/s) separations, and two additional faint narrow [CII]-emitting satellites. The overall system belongs to a larger-scale protocluster environment and is coincident to one of its overdensity peaks. ALMA reveals also the presence of [CII] emission arising from a circumgalactic gas structure, extending out to ~30 kpc. Our morpho-spectral decomposition analysis shows that about 50% of the total flux resides between the individual galaxy components, in a metal-enriched gaseous envelope characterized by a disturbed morphology and complex kinematics. Similarly to observations of shock-excited [CII] emitted from tidal tails in local groups, our results can be interpreted as a possible signature of interstellar gas stripped by strong gravitational interactions, with a possible contribution from material ejected by galactic outflows and emission triggered by star formation in small faint satellites. Our findings suggest that mergers could be an efficient mechanism of gas mixing in the circumgalactic medium around high-z galaxies, and thus play a key role in the galaxy baryon cycle at early epochs.