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Strongly Coupled Coherent Phonons in Single-Layer MoS2.

Accepted version
Peer-reviewed

Type

Article

Change log

Authors

Miranda, Henrique PC 
Molina-Sánchez, Alejandro 
Borrego-Varillas, Rocío 
Manzoni, Cristian 

Abstract

We present a transient absorption setup combining broadband detection over the visible-UV range with high temporal resolution (∼20 fs) which is ideally suited to trigger and detect vibrational coherences in different classes of materials. We generate and detect coherent phonons (CPs) in single-layer (1L)-MoS2, as a representative semiconducting 1L-transition metal dichalcogenide (TMD), where the confined dynamical interaction between excitons and phonons is unexplored. The coherent oscillatory motion of the out-of-plane A'1 phonons, triggered by the ultrashort laser pulses, dynamically modulates the excitonic resonances on a time scale of few tens of fs. We observe an enhancement by almost 2 orders of magnitude of the CP amplitude when detected in resonance with the C exciton peak, combined with a resonant enhancement of CP generation efficiency. Ab initio calculations of the change in the 1L-MoS2 band structure induced by the A'1 phonon displacement confirm a strong coupling with the C exciton. The resonant behavior of the CP amplitude follows the same spectral profile of the calculated Raman susceptibility tensor. These results explain the CP generation process in 1L-TMDs and demonstrate that CP excitation in 1L-MoS2 can be described as a Raman-like scattering process.

Description

Keywords

ab initio calculation, coherent phonons, exciton−phonon interaction, transient absorption spectroscopy, transition metal dichalcogenides

Journal Title

ACS Nano

Conference Name

Journal ISSN

1936-0851
1936-086X

Volume Title

14

Publisher

American Chemical Society (ACS)
Sponsorship
Royal Society (TG102524)
Engineering and Physical Sciences Research Council (EP/K01711X/1)
Engineering and Physical Sciences Research Council (EP/K017144/1)
European Commission (604391)
Engineering and Physical Sciences Research Council (EP/L016087/1)
European Commission Horizon 2020 (H2020) Future and Emerging Technologies (FET) (696656)
EPSRC (via University of Manchester) (R119256)
European Commission Horizon 2020 (H2020) Future and Emerging Technologies (FET) (785219)
European Research Council (842251)
Engineering and Physical Sciences Research Council (EP/G042357/1)
The Royal Society (wm090070)
European Research Council (319277)
European Commission Horizon 2020 (H2020) Future and Emerging Technologies (FET) (820378)
European Commission Horizon 2020 (H2020) Future and Emerging Technologies (FET) (881603)