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Low-energy electron ionization mass spectrometer for efficient detection of low mass species.

Published version
Peer-reviewed

Type

Article

Change log

Authors

Bergin, M 
Ward, DJ 
Lambrick, SM 
von Jeinsen, NA 
Holst, B 

Abstract

The design of a high-efficiency mass spectrometer is described, aimed at residual gas detection of low mass species using low-energy electron impact, with particular applications in helium atom microscopy and atomic or molecular scattering. The instrument consists of an extended ionization volume, where electrons emitted from a hot filament are confined using a solenoidal magnetic field to give a high ionization probability. Electron space charge is used to confine and extract the gas ions formed, which are then passed through a magnetic sector mass filter before reaching an ion counter. The design and implementation of each of the major components are described in turn, followed by the overall performance of the detector in terms of mass separation, detection efficiency, time response, and background count rates. The linearity of response with emission current and magnetic field is discussed. The detection efficiency for helium is very high, reaching as much as 0.5%, with a time constant of (198 ± 6) ms and a background signal equivalent to an incoming helium flux of (8.7 ± 0.2) × 106 s-1.

Description

Keywords

3401 Analytical Chemistry, 5106 Nuclear and Plasma Physics, 5110 Synchrotrons and Accelerators, 3406 Physical Chemistry, 34 Chemical Sciences, 51 Physical Sciences

Journal Title

Rev Sci Instrum

Conference Name

Journal ISSN

0034-6748
1089-7623

Volume Title

92

Publisher

AIP Publishing

Rights

Publisher's own licence
Sponsorship
Engineering and Physical Sciences Research Council (EP/E004962/1)
Engineering and Physical Sciences Research Council (EP/R008272/1)
EPSRC (EP/T00634X/1)