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Luminescent (metallo-supramolecular) cross-linked lanthanide hydrogels from a btp (2,3-bis(1,2,3-triazol-4-yl)picolinamide) monomer give rise to strong Tb(iii) and Eu(iii) centred emissions

Published version
Peer-reviewed

Repository URI

https://www.repository.cam.ac.uk/handle/1810/345937

Repository DOI

https://doi.org/10.17863/CAM.93359

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Bibliographic metadata (170.23 KB)
 Supporting information (6.09 MB)
 Published version (1.29 MB)

Type

Article

Change log

Authors

Hegarty, IN 
Bradberry, SJ 
Lovitt, JI 
Delente, JM 
Willis-Fox, N 
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Abstract

jats:pThe synthesis and study of the lanthanide luminescent 2,3-bis(1,2,3- triazol-4-yl)picolinamide (btp) based hydrogels F1 and F2 is described where Tb(jats:sciii</jats:sc>) or Eu(jats:sciii</jats:sc>) are also used to crosslink the btp units within the polymers.</jats:p>

Description

Acknowledgements: We thank the School of Chemistry TCD, Science Foundation Ireland (SFI PI Awards 10/IN.1/B2999 and 13/IA/1865 to TG). TG would also like to thank the SFI funded AMBER Centre for financial support (SFI 12/RC/2278_P2). EPSRC EP/S009000/1 is acknowledged for support of Dr Niamh Willis-Fox.

Keywords

3402 Inorganic Chemistry, 3403 Macromolecular and Materials Chemistry, 40 Engineering, 34 Chemical Sciences

Journal Title

Materials Chemistry Frontiers

Conference Name

Journal ISSN

2052-1537
2052-1537

Volume Title

Publisher

Royal Society of Chemistry (RSC)

Publisher DOI

https://doi.org/10.1039/d2qm00998f

Rights

Attribution 3.0 International Repository logo
Sponsorship
Engineering and Physical Sciences Research Council (EP/S009000/1)

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