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Inter-adsorbate forces and coherent scattering in helium spin-echo experiments.

Accepted version
Peer-reviewed

Type

Article

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Authors

Ward, David J 
Raghavan, Arjun 
Tamtögl, Anton 
Jardine, Andrew P 
Bahn, Emanuel 

Abstract

In studies of dynamical systems, helium atoms scatter coherently from an ensemble of adsorbates as they diffuse on the surface. The results give information on the co-operative behaviour of interacting adsorbates and thus include the effects of both adsorbate-substrate and adsorbate-adsorbate interactions. Here, we discuss a method to disentangle the effects of interactions between adsorbates from those with the substrate. The result gives an approximation to observations that would be obtained if the scattering was incoherent. Information from the experiment can therefore be used to distinguish more clearly between long-range inter-adsorbate forces and the short range effects arising from the local lattice potential and associated thermal excitations. The method is discussed in the context of a system with strong inter-adsorbate interactions, sodium atoms diffusing on a copper (111) surface.

Description

Keywords

cond-mat.mtrl-sci, cond-mat.mtrl-sci, cond-mat.mes-hall

Journal Title

Phys Chem Chem Phys

Conference Name

Journal ISSN

1463-9076
1463-9084

Volume Title

23

Publisher

Royal Society of Chemistry (RSC)

Rights

All rights reserved
Sponsorship
EPSRC (EP/T00634X/1)
Engineering and Physical Sciences Research Council (EP/E004962/1)