Vertically aligned two-dimensional SnS₂ nanosheets with a strong photon capturing capability for efficient photoelectrochemical water splitting

Thumbnail Image
Change log
Liu, G 
Li, Z 
Chen, X 
Zheng, W 

Two-dimensional (2D) metal dichalcogenides have emerged as attractive materials for application in photoelectrochemical (PEC) water splitting due to their unique structure and strong interaction with light. To date, deposition of exfoliated 2D nanosheet dispersions onto conductive substrates by a variety of techniques (e.g. casting, spin-coating and self-assembly) has been the most exploited approach to fabricate photoelectrodes from these materials. However, such solution processing strategies do not allow for control over the flake orientation and formation of intimate electrical contacts with conductive substrates. This could negatively affect the PEC efficiency. Herein, we demonstrate, for the first time, vertically aligned 2D SnS₂ nanosheets with controllable growth and density on conductive substrates (FTO and carbon cloth (CC)) by a modified chemical vapor deposition (CVD) method. In PEC measurements, these vertically aligned 2D SnS₂ nanosheet photoelectrodes exhibit a high incident photon to current conversion efficiency (IPCE) of up to 40.57% for SnS₂⊥CC and 36.76% for SnS₂⊥FTO at 360 nm, and a high photocurrent density of up to 1.92 ± 0.01 mA cm‾² for SnS₂⊥CC and 1.73 ± 0.01 mA cm‾² for SnS₂⊥FTO at 1.4 V vs. reversible hydrogen electrode (RHE). These values are two times higher than that of their photoelectrode (SnS₂//FTO) counterparts prepared by conventional spin-coating. Our demonstration of this controllable growth strategy offers a versatile framework towards the design and fabrication of high performance PEC photoelectrodes based on 2D metal chalcogenides.

3403 Macromolecular and Materials Chemistry, 34 Chemical Sciences, 3406 Physical Chemistry, 40 Engineering, 4016 Materials Engineering, 4018 Nanotechnology, 7 Affordable and Clean Energy
Journal Title
Journal of Materials Chemistry A
Conference Name
Journal ISSN
Volume Title
Royal Society of Chemistry
National Natural Science Foundation of China (NSFC, No. 61390502, 61172001,21373068); National Basic Research Program of China (2013CB632900); Royal Academy of Engineering