Repository logo
 

Tracking Optical Welding through Groove Modes in Plasmonic Nanocavities.

Accepted version
Peer-reviewed

Type

Article

Change log

Authors

Mertens, J 
Demetriadou, A 
Bowman, RW 
Benz, F 
Kleemann, M-E 

Abstract

We report the light-induced formation of conductive links across nanometer-wide insulating gaps. These are realized by incorporating spacers of molecules or 2D monolayers inside a gold plasmonic nanoparticle-on-mirror (NPoM) geometry. Laser irradiation of individual NPoMs controllably reshapes and tunes the plasmonic system, in some cases forming conductive bridges between particle and substrate, which shorts the nanometer-wide plasmonic gaps geometrically and electronically. Dark-field spectroscopy monitors the bridge formation in situ, revealing strong plasmonic mode mixing dominated by clear anticrossings. Finite difference time domain simulations confirm this spectral evolution, which gives insights into the metal filament formation. A simple analytic cavity model describes the observed plasmonic mode hybridization between tightly confined plasmonic cavity modes and a radiative antenna mode sustained in the NPoM. Our results show how optics can reveal the properties of electrical transport across well-defined metallic nanogaps to study and develop technologies such as resistive memory devices (memristors).

Description

Keywords

2D materials, Plasmonic nanocavities, light-induced plasmonic welding, nanoparticle on mirror, plasmonic hybridisation, tuneable plasmonics

Journal Title

Nano Lett

Conference Name

Journal ISSN

1530-6984
1530-6992

Volume Title

16

Publisher

American Chemical Society (ACS)
Sponsorship
Engineering and Physical Sciences Research Council (EP/G060649/1)
Engineering and Physical Sciences Research Council (EP/L027151/1)
European Research Council (320503)
Engineering and Physical Sciences Research Council (EP/K035282/1)
Engineering and Physical Sciences Research Council (EP/G037221/1)
Engineering and Physical Sciences Research Council (EP/L015978/1)
Engineering and Physical Sciences Research Council (Grant IDs: EP/ G060649/1, EP/L027151/1, EP/G037221/1, EPSRC NanoDTC EP/L015978/1), European Research Council (Grant ID: LINASS 320503), Winton Programme of the Physics of Sustainability, Project FIS2013- 41184-P from MINECO and IT756-13 from the Basque Government consolidated groups
Relationships
Is supplemented by: